Know Your Alcohols!

Know your Alcohols!

You might know ethanol from malbec and martinis, and isopropl alcohol from the first-aid kit. But did you know that some alcohols are moisturizing for the skin and hair? Alcohols are diverse and have a wide range of functions. Some are liquid at room temperature, others are solid, some condition your skin and hair, and some are disinfectants! Here are some good reasons to learn about alcohols:

1. To know if an ingredient is a moisturizer or will be drying
2. To know if a product contains a "hidden" conflict ingredient
3. To demystify product labels

Different Types of Alcohols

Alcohols are produced in plants, animals, microorganisms and fungi, and they play diverse metabolic and physiological roles. Some alcohols are produced industrially from organic molecules such as fossil carbons found in nature. Read on to learn about some common types of alcohols! We'll start with fatty alcohols, which are widely used in skin and hair care.

Fatty Alcohols

Photo by Sora Shimazaki from Pexels

Fatty alcohols are long-chain organic compounds produced by plants, animals and bacteria. [Technically speaking they're aliphatic molecules (molecules without aromatic ring structures).] Lipids and waxes in animals and plants contain fatty alcohols. Waxes and fats play many roles, including energy storage and protection of cells.

Fatty alcohols are widely used in skin and hair care cosmetics. A common example is cetyl alcohol, which we use in our conditioner bars. Cetyl alcohol compound was originally derived from whale oil – the name "cetyl" comes from from Cetaceae, the Order that encompasses aquatic mammals. Cetyl alcohol is now most commonly derived from coconut oil and palm oil. We attempt to source our cetyl alcohol from coconut oil, but this is not always possible.

Fatty alcohols are important conditioners and thickeners in skin and hair care products. They act as emollients that soothe and soften skin, and as occlusives that reduce water loss. Fatty alcohols are usually solid at room temperature and have a waxy texture. Fatty alcohols moisturize the skin and hair, they are not drying.

Fermented Alcohols

Fermentation vessels. Image by Tibor Janosi Mozes from Pixabay

Ethanol, probably the best known alcohol, is produced through fermentation. Fermentation is the microbial breakdown of sugars and starches in fruits, grains, sugarcane, and other organic materials. Ethanol (ethyl alcohol) can be distilled to remove water and other "impurities." Distillation concentrates the alcohol. Because it's small and has a charged part (the OH) and a non-charged part (the short Carbon chain), ethanol is a powerful and versatile solvent. It's soluble in water and can also dissolve nonpolar (noncharged) molecules.

Short-chain liquid alcohols like ethanol disrupt microbial cell walls, which makes them useful disinfectants. These alcohols are a primary ingredient in cleaning products including hand sanitizers. Ethanol is highly flammable and used as a fuel additive. This is controversial because ethanol decreases fuel efficiency and its production requires large amounts of energy and agricultural land.

Petroleum-Based Alcohols

Photo by Karolina Grabowska from Pexels

Some alcohols are derived from fossil fuels (petroleum), the most ancient organic matter on Earth. A prime example is isopropyl alcohol (IPA). IPA is produced from propane (natural gas). Isopropyl alcohol is a common disinfectant used in hand sanitizers and other cleaning products. IPA evaporates quickly without leaving a residue.

Sugar Alcohols

Image by 41330 from Pixabay

Alcohols with 3 or more OH groups are called polyols (alcohols with 2 OH groups are called diols). One class of polyols is the sugar alcohols, such as xylitol, sorbitol, glycerol, mannitol and erythryol. Sugar alcohols are produced by plants, algae and fungi. They're involved in  plant metabolic processes and are a significant component of photosynthetic production.

Sugar alcohols are edible sweeteners.  They contain fewer calories than glucose and sucrose, but they're not as digestible so can cause bloating and diarrhea.

The Chemical Structure of Alcohols

Chemically speaking, alcohols are organic compounds that have an OH (hydroxyl) group attached to a saturated Carbon atom (a Carbon atom with no double bonds).

Ball-and-stick model of an alcohol molecule (R3COH). The red and white balls represent the hydroxyl group (-OH). The "R's" represent Carbon-Hydrogen groups. The grey ball is a Carbon atom. By SubDural12, Wikimedia Commons.

Many alcohols are made of small molecules, with chain lengths of 3 or fewer carbon atoms. For example, ethanol (CH₃CH₂OH) contains only 2 carbons. The OH group makes these small, liquid alcohols highly soluble in water.

Some alcohols have long carbon chains and are viscous or solid at room temperature. Take cetyl alcohol (an ingredient in our conditioner bars), for example (CH₃(CH₂)₁₅OH). Long-chain alcohols are dominated by the hydrocarbon part of the chain. They look, feel andn act like fats and waxes. Compare the shape and size of ethanol and cetyl alcohol molecules below:

3D model of ethanol (CH3CH2OH) (Wikimedia Commons). The grey balls represent Hydrogen atoms, the black balls represent Carbon atoms, and the red ball indicates Oxygen. The Oxygen atom has a strong negative charge that makes this small molecule very soluble in water.

3D model of cetyl alcohol (CH3(CH2)15OH) (Wikimedia Commons). The color scheme is the same as for ethanol (the Carbons are on the inside of the model). Because the Carbon chain is so long, it dominates the behavior of this molecule and makes it much less soluble in water compared to alcohols with small molecular sizes.

The Diverse World of Alcohols

As you can see, alcohols are a diverse group of compounds with many different structures and functions. Knowing a bit about them can help you understand ingredient labels and make informed choices about what you put in and on your body.

One Earth Conditioner Bars

Experience the lovliness of fatty acohols first hand with a One Earth Conditioner Bar!